How to use this calculator
Only one input is needed, because at 25 °C the four quantities are locked together by the ion product of water. Enter a pH-meter reading to get the ion concentrations, or enter a concentration (for a strong acid or base, the concentration of the acid or base itself) to get pH. Very small concentrations can be typed in scientific notation, such as 3.2e-9.
Concentration fields accept M, mM, µM and nM. For a strong monoprotic acid like HCl, [H⁺] equals the acid concentration; for a strong base like NaOH, [OH⁻] equals the base concentration. Weak acids only partly dissociate, so [H⁺] must first be found from the acid dissociation constant K_a.
The formula
- pH
- ph
- pOH
- poh
- [H⁺]
- hydrogen ion concentration
- [OH⁻]
- hydroxide ion concentration
Worked example
A dilute hydrochloric acid solution has a hydrogen ion concentration of 1 mM (0.001 mol/L).
- pH = −log₁₀(0.001) = 3.
- pOH = 14 − 3 = 11.
- [OH⁻] = 10⁻¹¹ mol/L.
pH 3 is strongly acidic, roughly the acidity of vinegar or soda.
Assumptions and limits
- Temperature is 25 °C, where K_w = 1.0 × 10⁻¹⁴. At 37 °C neutral water has pH ≈ 6.8.
- Concentrations stand in for activities, which is accurate for dilute solutions (below roughly 0.1 M).
- Very dilute acids (below 10⁻⁶ M) are dominated by water self-ionization; the simple formula will understate pH.
Frequently asked questions
Can pH be negative?
Yes. Concentrated strong acids above 1 M have negative pH; 10 M HCl is about pH −1 on the concentration scale.
Is pH 7 always neutral?
Only at 25 °C. Neutral means [H⁺] = [OH⁻], which occurs at pH 7.47 at 0 °C and about pH 6.14 at 100 °C.
How much more acidic is pH 3 than pH 5?
The scale is logarithmic, so each unit is a factor of ten. pH 3 has 100 times the hydrogen ion concentration of pH 5.
Sources
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