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pH Calculator

Type any one of pH, pOH, [H⁺] or [OH⁻] and the other three are filled in, assuming water at 25 °C.

By Dr. Priya Nair, science writer and former university physics lecturer · Updated

pH Calculator

Enter any 1 known values — the others are solved as you type. Change units at any time.

Fill in the values you know.

How to use this calculator

Only one input is needed, because at 25 °C the four quantities are locked together by the ion product of water. Enter a pH-meter reading to get the ion concentrations, or enter a concentration (for a strong acid or base, the concentration of the acid or base itself) to get pH. Very small concentrations can be typed in scientific notation, such as 3.2e-9.

Concentration fields accept M, mM, µM and nM. For a strong monoprotic acid like HCl, [H⁺] equals the acid concentration; for a strong base like NaOH, [OH⁻] equals the base concentration. Weak acids only partly dissociate, so [H⁺] must first be found from the acid dissociation constant K_a.

The formula

pH = −log₁₀[H⁺]
pOH = −log₁₀[OH⁻]
pH + pOH = 14 (25 °C)
pH
ph
pOH
poh
[H⁺]
hydrogen ion concentration
[OH⁻]
hydroxide ion concentration

Worked example

A dilute hydrochloric acid solution has a hydrogen ion concentration of 1 mM (0.001 mol/L).

  1. pH = −log₁₀(0.001) = 3.
  2. pOH = 14 − 3 = 11.
  3. [OH⁻] = 10⁻¹¹ mol/L.

pH 3 is strongly acidic, roughly the acidity of vinegar or soda.

Assumptions and limits

  • Temperature is 25 °C, where K_w = 1.0 × 10⁻¹⁴. At 37 °C neutral water has pH ≈ 6.8.
  • Concentrations stand in for activities, which is accurate for dilute solutions (below roughly 0.1 M).
  • Very dilute acids (below 10⁻⁶ M) are dominated by water self-ionization; the simple formula will understate pH.

Frequently asked questions

Can pH be negative?

Yes. Concentrated strong acids above 1 M have negative pH; 10 M HCl is about pH −1 on the concentration scale.

Is pH 7 always neutral?

Only at 25 °C. Neutral means [H⁺] = [OH⁻], which occurs at pH 7.47 at 0 °C and about pH 6.14 at 100 °C.

How much more acidic is pH 3 than pH 5?

The scale is logarithmic, so each unit is a factor of ten. pH 3 has 100 times the hydrogen ion concentration of pH 5.

Sources

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